Using the sun to create hydrogen fuel

Ceria-unit-cell-3D-ionicImage via Wikipedia
BBC:

A prototype solar device has been unveiled which mimics plant life, turning the Sun's energy into fuel.

The machine uses the Sun's rays and a metal oxide called ceria to break down carbon dioxide or water into fuels which can be stored and transported.

Conventional photovoltaic panels must use the electricity they generate in situ, and cannot deliver power at night.

Details are published in the journal Science.

The prototype, which was devised by researchers in the US and Switzerland, uses a quartz window and cavity to concentrate sunlight into a cylinder lined with cerium oxide, also known as ceria.

Ceria has a natural propensity to exhale oxygen as it heats up and inhale it as it cools down.

If as in the prototype, hydrogen and/or water are pumped into the vessel, the ceria will rapidly strip the oxygen from them as it cools, creating hydrogen and/or carbon monoxide.

Hydrogen produced could be used to fuel hydrogen fuel cells in cars, for example, while a combination of hydrogen and carbon monoxide can be used to create "syngas" for fuel.

It is this harnessing of ceria's properties in the solar reactor which represents the major breakthrough, say the inventors of the device. They also say the metal is readily available, being the most abundant of the "rare-earth" metals.

...
The Guardian says the process mimics how plants use the sun. A rooftop device would only crate about three gallons of hydrogen which would not get you very for or fuel a generator through the night. If they can make the device more efficient it has some potential and does not sound like it would be too costly.
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